Thursday, July 30, 2009

Catholic Scientist-Philosopher 4: PIERRE DUHEM

Pierre Duhem

Pierre Maurice Marie Duhem (10 June 186114 September 1916) was a French physicist, mathematician and philosopher of science, best known for his writings on the indeterminacy of experimental criteria and on scientific development in the Middle Ages. Duhem also made major contributions to the science of his day, particularly in the fields of hydrodynamics, elasticity, and thermodynamics.
Oresmes-Nicole, a Catholic philosopher scientist of the Middle Ages. Miniature of Nicole Oresmes Traité de l’espere, Bibliothèque Nationale, Paris, France, fonds français 565, fol. 1r.
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HISTORY OF SCIENCE
Duhem is well known for his work on the history of science, which resulted in the ten volume Le système du monde: histoire des doctrines cosmologiques de Platon à Copernic (The System of World: A History Cosmological Doctrines from Plato to Copernicus).[5 Duhem, Pierre (1914). Le système du monde: histoire des doctrines cosmologiques de Platon à Copernic (The System of World: A History Cosmological Doctrines from Plato to Copernicus)] Unlike many former historians (e.g. Voltaire and Condorcet), who denigrated the Middle Ages, he endeavored to show that the Roman Catholic Church had helped foster Western science in one of its most fruitful periods. His work in this field was originally prompted by his research into the origins of statics, where he encountered the works of medieval mathematicians and philosophers such as John Buridan, Nicole Oresme and Roger Bacon, whose sophistication surprised him. He consequently came to regard them as the founders of modern science, having in his view anticipated many of the discoveries of Galileo Galilei and later thinkers. Duhem concluded that "the mechanics and physics of which modern times are justifiably proud to proceed, by an uninterrupted series of scarcely perceptible improvements, from doctrines professed in the heart of the medieval schools."[6. Duhem, Pierre. Les origines de la statique (The Origins of the Static). 1. Harvard University Press. pp. 38. ]
Cathedrale NOTRE DAME DE PARIS

LIFE AND WORKS [Cf. "Stanford Encyclopedia of Philosophy"]

Pierre Maurice Marie Duhem was born on June 10, 1861, in Paris, in a modest neighborhood on the Rue des Jeûneurs, near the Grands Boulevards, just South of Montmartre. His father, Pierre-Joseph Duhem, was of Flemish origin, the oldest child of a large family who lived in the French northern industrial city of Roubaix, near the Belgian border. After the death of his parents, Pierre-Joseph was forced to discontinue his studies with the Jesuits in order to provide for the family. He worked in the textile industry as a sales representative, but never abandoned his love of learning; it is said that, late in life, he was seen everywhere with the work of a Latin author under his arm. Pierre Duhem's mother, Marie-Alexandrine Fabre, descended on her mother's side from the Hubault-Delormes, a bourgeois family who had settled in Paris during the seventeenth century. Her father's family had originally come from the southern town of Cabesprine, near Carcasonne, and it was there, in a house they still maintained and to which Pierre returned most summers, that he died on September 14, 1916.

The Duhems made sure that Pierre was well educated. Starting at the age of seven he was given private lessons with a small group of students, on grammar, arithmetic, Latin, and catechism. A letter he wrote about the siege of Chateaudun he experienced in October 1870 attests to his being already a literate writer by the age of nine. The young Duhem was witness to some troubling times, with the Franco-Prussian War raging until the armistice in February 1871 and the Paris Commune in March. The Duhems had avoided the advance of the Prussians against Paris but were caught up in the siege of Chateaudun; they barely escaped to Bordeaux, returning to Paris after the armistice and just before the Paris Commune. That social experiment lasted only two months, though it set the stage for some wide-ranging transformations to French culture that were to have great consequences when they were later established permanently. Among the Commune's decrees were the separation of church from state, the rendering of all church property into public property, and the exclusion of religion from schools. The Duhems did not approve of these measures and were particularly chagrined by some of the extreme actions taken by the most radical elements of the Commune, such as the desecration of churches and graveyards. For the Duhems, the Commune was a paradigm of anarchy and irreligion.

The Fall of 1872 brought two great tragedies to the Duhem family: a diphtheria epidemic killed Pierre's younger sister Antoinette and his recently born brother Jean, leaving only Pierre and Antoinette's twin sister Marie. Pierre continued his education (as demi-pensionnaire) at a Catholic school, the Collège Stanislas in Paris, in 1872 and for the next ten years. The mature Duhem recalled his college days as most formative. In particular, he singled out his science teacher as an important influence:

Let us return to some twenty-five years back to the time when we received our first initiation as a physicist in the mathematics classes of the Collège Stanislas. The person who gave us this initiation, Jules Moutier, was an ingenious theorist; his critical sense, ever aware and extremely perspicacious, distinguished with sure accuracy the weak point of many a system that others accepted without dispute; proofs of his inquiring mind are not lacking, and physical chemistry owes him one of its most important laws. It was this teacher who planted in us our admiration for physical theory and the desire to contribute to its progress. … Being a disciple of Moutier, it was as a convinced partisan of mechanism that we approached the courses in physics pursued at the Ecole Normale. (1914, 417-18; 1954, 275-76.)
Duhem's science teacher Jules Moutier went on to teach at the Ecole Polytechnique and to publish a number of texts, including La thermodynamique et ses principales applications (Paris: Gauthier-Villars, 1885). Duhem recognized in his theory of chemical dissociation and in his thermodynamics generally a first enunciation of the chemical theories that Josiah Willard Gibbs, an important later influence on Duhem, was to develop more fully.

In 1882 Duhem enrolled at the prestigious secular institution of higher education, the Ecole Normale Supérieure. When he entered the Ecole Normale he was first in his class in the Science Section, out of the approximately 30 students chosen from the best 800 or so graduates in France that year, and he remained first throughout his years there. The curriculum at the Ecole Normale usually lasted three years; Duhem was granted a fourth year and stayed on a fifth year as agrégé préparateur. He received a license in mathematics and another in physics at the end of academic year 1883-84. In his final year, Duhem was offered a position in Louis Pasteur's laboratory as a chemist-bacteriologist, though he refused it because of his desire to work in theoretical physics.

One of the turning points in Duhem's career occurred during academic year 1884-85, while he was only a third-year student. Duhem presented a thesis in physics for his doctorate. The thesis, on thermodynamic potential, Le potentiel thermodynamique et ses applications à la mécanique chimique et à l'étude des phénomènes électriques, was rejected by a panel composed of three scholars: the physicist Gabriel Lippmann and the mathematicians Charles Hermite and Emile Picard. The panel, chaired by Lippmann, seems to have made a political decision. The prestigious French scientific publisher, Hermann, published a version of the thesis the following year. Duhem defended another thesis in applied mathematics, on the theory of magnetization by induction, Sur l'aimantation par influence, and received his doctorate in October 1888; this time, the physicist Edmond Bouty, the mathematician Gaston Darboux, and the mathematician-physicist Henri Poincaré constituted the panel that accepted the dissertation. It would be difficult to understand fully these events without delving deeply into the social, cultural, and intellectual context of France at the end of the nineteenth century. At a time when French scientists were predominantly liberal and anti-clerical, Duhem was openly conservative and deeply religious; he was also stubborn and often contentious. The structure of French academia was surely also a factor in the affair. However, the specific motives generally cited in the case were Lipmann's “jealousy” and the fact that Duhem's thesis refuted the principle of maximum work: that chemical changes tend spontaneously to produce maximum heat. It was one of the cherished theses of Marcelin Berthelot, Lippmann's friend and a significant power in the French scientific establishment. It was reported that Berthelot had said: “This young man will never teach in Paris.” Berthelot's edict came true. Duhem spent his academic career in provincial universities far from Paris, the center of academic life in France. His teaching positions brought him from Lille, then briefly to Rennes, then to Bordeaux for the remainder of his life, but never to Paris.

Duhem assumed the position of Maitre de Conférences at the Faculté des Sciences at Lille in October 1887. There he met Adèle Chayet, whom he married in October 1890. Their daughter Hélène was born in September 1891. Tragically, Adèle died in childbirth the following summer; the newborn child also did not survive. Duhem never remarried. He left the upbringing of Hélène to his mother who lived with him after his father Pierre-Joseph died. The situation in Lille soured for Duhem. Never one to back off from a dispute, he fought with the Dean of his faculty over a minor issue: an assistant had failed to unlock the door of Duhem's laboratory for his students during their licentiate examinations. The assistant complained about his mistreatment by Duhem to the Dean, who requested that the assistant write a letter of apology; Duhem rejected the apology and took issue with the Dean, who then brought the matter to the Rector, adding further complaints against Duhem. The minor issue having escalated to immense proportions, Duhem requested and received a change of positions at the end of academic year 1893. During these formative years, Duhem worked very hard on his science. He published six books: a two-volume work on hydrodynamics, elasticity, and acoustics, his lectures on electricity and magnetism, in three volumes, and an introduction to physical chemistry. Duhem was one of the first to appreciate the work of W. J. Gibbs, writing the earliest critical examination of Gibbs' “On the Equilibrium of Heterogeneous Substances” in 1887 and later promoting the French translation of Gibbs' works (Duhem 1907).

In October 1893, Duhem left Lille for Rennes. He lasted only one year, leaving for Bordeaux in October 1894. He was hoping for a position in Paris. The prodigious quantity and quality of his publications in many fields of science, the philosophy of science, and the history of science were not able to change his situation. Very late in life, he was approached about the newly created chair in the History of Science at the Collège de France, but he refused to be a candidate for it. The proud and stubborn Duhem told his daughter: “I am a theoretical physicist. Either I will teach theoretical physics at Paris or else I will not go there.”

Duhem's curriculum vitae, written in 1913, on the occasion of his nomination as non-resident member of the Académie des Sciences (1917, 41-70), lists over 350 items, about 50 of which were books. From the mid-1880s to 1900, Duhem's primary interests were scientific, ranging from thermodynamics and physics, but publishing on elasticity and energetics as late as 1911. In the 1890s, while still at Lille, he began writing essays on questions of methodology that would lead to the publication of his most influential books in the philosophy of science, translated into English as The Aim and Structure of Physical Theory and To Save the Phenomena. It was also in the mid-1890s that Duhem published his first essays in the history of science, starting on the path that would lead him in 1904 to a new understanding of the history of science and to his thesis of continuity between medieval and early modern science. This path would culminate in such important historical works as Études sur Léonard de Vinci and Le système du monde.

Duhem made a number of enduring contributions to thermodynamics and physical chemistry. Among these were the Duhem–Margules and Gibbs–Duhem equations, which deal with reversible processes in thermodynamics as quasi-static limiting processes and give a general proof of the Gibbs phase rule. These results were obtained in the context of a program of generalized thermodynamics called “energetics.” Indeed, Duhem's entire scientific program was driven by the conviction that a generalized thermodynamics should be foundational for physical theory, thinking that all of chemistry and physics, including mechanics, electricity and magnetism, should be derivable from thermodynamic first principles. Duhem started from the concept of the thermodynamic potential (the topic of his failed thesis), deploying it in a manner similar to that of potentials in mechanics, so as to represent all physical and chemical changes. The program finds its mature statement in his Traité d'énergétique of 1911; it was well received by late-nineteenth-century energeticists, such as Wilhelm Ostwald and Georg Helm. So important was energetics for Duhem, that his work in the history and philosophy of science has been viewed as an attempt to defend its aims and methods (see Lowinger 1941). More recently, Niall Martin and others have argued for the importance of religious motives in Duhem's work (see Martin 1991, Jaki 1991) and it has become clear in the course of Duhem's writings that he expected the endpoint of science to harmonize with the teachings of the Catholic Church.

Whatever was Duhem's initial motivation, his historical and philosophical work took on a life of its own. One cannot read Duhem's numerous historical and philosophical tomes and think that his labor was only in the service of energetics and that the sole goal of his works was but a defense of its methods and its historical position. No doubt energetics might be a thread running through Duhem's various works, and no doubt these works harmonize with the method of energetics as he conceives it, but energetics cannot be the whole story.

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